Product ID:GENETRON 113 TRICHLOROTRIFLUOROETHANE
MSDS Date:02/01/1992
FSC:6830
NIIN:00F050805
MSDS Number: CCCZV

Emergency Phone: 201-455-2000

Info Phone: 201-455-4157

Cage: 0LYW2

Telephone: 804-520-3321

Cage: 0LYW2

FREON 113, 1,1,2,-TRICHLORO-1,2,2,-TRIFLUOROETHANE,

CAS: 76-13-1

RTECS: KJ4000000

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: CAN CAUSE IRRITATION OF
THE RESPIRATORY TRACT, CNS DEPRESSANT, CARDIAC EFFECTS & DEATH.
ASPHYXIATION HAZARD. INGESTION: RESPIRATORY FAILURE CAN OCCUR.
SKIN: IRRITATION/DERMATITIS, ABSORPTI ON CAN OCCUR. EYES:
IRRITATION & MAY CAUSE CONJUNCTIVITIS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:HEADACHE, DIZZINESS, NAUSEA, LOSS OF
COORDINATION, INTOXICATION, LOSS OF CONCENTRATION, RAPID
SUFFOCATION, IRRITATION, DEFATTING, ERYTHEMA, DISCOMFORT, PAIN.

First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR, PREFERABLY MOUTH
TO MOUTH/OXYGEN AS NECESSARY. DON'T GIVE ADRENALIN (EPINEPHRINE).
EYES: IMMEDIATELY FLUSH W/LARGE AMOUNTS OF WATER FOR 15 MINS. SKIN:
WASH P ROMPTLY W/SOAP & WATER FOR 15 MINS. INGESTION: DON'T INDUCE
VOMITING. DON'T GIVE STIMULANTS. OBTAIN MEDICAL ATTENTION IN ALL
CASES.

Extinguishing Media:USE AN EXTINGUISHING AGENT SUITABLE FOR SURROUNDING
FIRE.
Fire Fighting Procedures:WEAR NIOSH APPROVED PRESSURE DEMAND SCBA. USE
WATER SPRAY TO KEEP CONTAINERS COOL.
Unusual Fire/Explosion Hazard:MATERIAL IS NONFLAMMABLE, WILL DECOMPOSE
AT TEMPS >482F. AUTOIGNITION TEMP: 1256F.

Spill Release Procedures:EVACUATE PERSONNEL. REMOVE FLAMES & SHUT OFF
LEAK W/O RISK. ABSORB W/COMMERCIAL ABSORBENT, SHOVEL INTO METAL
DRUMS, CLOSE & STORE. DIKE UP LARGE AREA W/COMMERCIAL ABSORBENT &
PUMP INTO DRUMS, MAKING S URE PUMP DOESN'T OVERHEAT.

Handling and Storage Precautions:STORE IN A CLEAN, COOL, DRY & WELL
VENTILATED AREA OF LOW FIRE RISK. PROTECT CONTAINERS FROM PHYSICAL
DAMAGE & KEEP CLOSED.
Other Precautions:AVOID BREATHING VAPOR, LIQUID CONTACT W/EYES,
SKIN/CLOTHING. EMPTY CONTAINER MAY CONTAIN PRODUCT RESIDUES;
OBSERVE LABELED HAZARD PRECAUTIONS. CLOSURES SHOULD BE REMOVED
CAREFULLY & WHEN EMPTY AVOID A CCIDENTAL EXPOSURE TO ENTRAPPED
VAPORS.

Respiratory Protection:FOR ACCIDENTAL/NON-VENTILATED AREAS, USE A
SCBA/SUPPLIED AIR RESPIRATOR, APPROVED BY NIOSH.
Ventilation:LOCAL EXHAUST WHERE LEAKAGE IS PROBABLE. MECHANICAL
(GENERAL) FOR OPERATING & STORAGE AREAS.
Protective Gloves:IMPERVIOUS/POLY VINYL ALCOHOL/NEOPRENE
Eye Protection:CHEMICAL SAFETY GOGGLES/FACE SHIELD
Other Protective Equipment:PROTECTIVE CLOTHING, EYEWASH STATIONS &
QUICK DRENCH SHOWER FACILITIES.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE/DISCARD. DON'T WEAR CONTACT LENSES.
Supplemental Safety and Health

Boiling Pt:B.P. Text:117.68F
Melt/Freeze Pt:M.P/F.P Text:-31F
Decomp Temp:Decomp Text:482F
Vapor Pres:5.6
Vapor Density:6.5
Spec Gravity:1.57
pH:7
Evaporation Rate & Reference:(ETHER = 1): 1.3
Solubility in Water:0.035%
Appearance and Odor:COLORLESS LIQUID W/FAINT ETHERAL ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALUMINUM POWDER, BARIUM, LITHIUM, POWDERED TITANIUM, ACITVE METALS,
CALCIUM, POWDERED MAGNESIUM/ZINC, BERYLLIUM, ALLOYS.
Stability Condition to Avoid:OPEN FLAMES, HOT SPOTS, WELDING.
Hazardous Decomposition Products:THERMAL: TEMPS >482F, HYDROCHLORIC &
HYDROFLUORIC ACIDS, PHOSGENE.

Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.